FIELD: petrochemistry.
SUBSTANCE: invention relates to petrochemistry, to methods of producing alkaline alkylphenol (sulfophenolate) additives for lubricating oils. Invention relates to a method of producing sulfophenolate additives, involving reaction at elevated temperature of C8-C18 alkylphenol, sulphur and calcium oxide or hydroxide in the presence of ethylene glycol, a neutralization reaction at a first step, reaction of the obtained product with an additional amount of calcium oxide or hydroxide and ethylene glycol in a second step, followed by treatment with carbon dioxide, wherein the first stage of the process is carried out by introducing a diluent oil, which is used as esters of terephthalic acid in amount of 60-67% of the weight of alkylphenol, wherein first, when heated to temperature of 115-120 °C suspension of esters of terephthalic acid with calcium oxide or hydroxide, ethylene glycol and sulphur is prepared, then alkylphenol C8-C18 is added to the obtained mixture.
EFFECT: development of a method of producing an additive for lubricating oils, which enables to improve colloidal stability of solutions of additives, antioxidant and antifriction properties of commercial lubricants containing the additive.
2 cl, 1 tbl, 9 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PREPARING LUBRICANT OIL ADDITIVES | 2009 |
|
RU2398814C1 |
METHOD OF PREPARING LUBRICATING OIL ADDITIVES | 2000 |
|
RU2186833C2 |
METHOD FOR PRODUCING LUBRICANT ADDITIVES | 2015 |
|
RU2582124C1 |
METHOD OF PREPARING HIGH-ALKALINE LUBRICATING OIL ALKYLPHENOL ADDITIVES | 2003 |
|
RU2238303C1 |
METHOD OF PREPARING ADDITION AGENT FOR LUBRICATING OILS | 2000 |
|
RU2179996C1 |
LUBRICATION OIL ADDITIVE PREPARATION METHOD | 2002 |
|
RU2215022C1 |
METHOD OF PRODUCING LUBRICANT OIL ADDITIVES | 2017 |
|
RU2638294C1 |
PROCESS FOR PREPARING ADDITION AGENT, TO LUBRICATING OILS, AND LUBRICATING OIL | 1995 |
|
RU2076895C1 |
METHOD FOR PRODUCTION OF ADDITIVE FOR PETROLEUM PRODUCTS AND COMPOSITIONS COMPRISING IT | 1995 |
|
RU2083644C1 |
METHOD OF DETERMINING SUPERALKALINE ADDITIVE FOR LUBRICATION OILS | 2003 |
|
RU2241740C1 |
Authors
Dates
2025-03-05—Published
2024-07-01—Filed