FIELD: chemistry.
SUBSTANCE: group of inventions relates to a zeolite-containing oligomerisation catalyst, a method for preparation and use thereof. Described is a method which includes preparing a support obtained with the addition of a binding component, which is added without pre-wetting the zeolite with water, using as a peptizing module an aqueous solution of nitric acid with concentration of 15-30 wt.%, decontaminating the outer surface of the crystalline zeolite of type ZSM-5 by treating with an organosilicon compound at a catalyst moulding step and subsequent calcination, wherein active component used is zeolite ZSM-5 with molar ratio Si/Al equal to 20-1070. Invention also describes a zeolite-containing oligomerisation catalyst and use of the zeolite-containing catalyst for oligomerisation of olefin-containing fractions of hydrocarbons.
EFFECT: zeolite-containing oligomerisation catalyst with improved properties which enable to reduce coke formation and prolong the duration of the cycle between regeneration runs, a method for preparation and use thereof.
10 cl, 1 tbl, 13 ex
Title | Year | Author | Number |
---|---|---|---|
HIGH-SILICON ZEOLITE-CONTAINING OLIGOMERIZATION CATALYST, METHOD FOR ITS PREPARATION AND USE | 2022 |
|
RU2792590C1 |
ZEOLITE-CONTAINING OLIGOMERIZATION CATALYST AND METHOD OF ITS PRODUCTION | 2016 |
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RU2633882C1 |
METHOD FOR PRODUCING PETROL FUEL HYDROCARBONS FROM OLEFINS | 2016 |
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RU2644781C2 |
METHOD OF MODIFYING CRYSTALLINE ZEOLITE ZSM-5 AND USE OF OBTAINED ZEOLITE WITH DEACTIVATED EXTERNAL SURFACE | 2013 |
|
RU2555879C2 |
APPLICATION OF OLIGOMERIZATION CATALYST FOR PRODUCTION OF GASOLINE OR CONCENTRATES OF AROMATIC COMPOUNDS DURING JOINT PROCESSING OF HYDROCARBON FRACTIONS, OXYGENATES AND OLEFIN-CONTAINING FRACTIONS | 2022 |
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RU2803735C1 |
METHOD OF PRODUCING PETROL FACTIONS FROM OLEFIN-CONTAINING GASES | 2016 |
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RU2635110C1 |
METHOD OF PREPARING MOTOR GASOLINE | 1996 |
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RU2117030C1 |
CATALYST AND METHOD FOR OLIGOMERIZATION OF LOWER OLEFINS | 1999 |
|
RU2151001C1 |
METHOD OF PROCESSING OLEFIN-CONTAINING FEEDSTOCK (OPTIONS) | 2001 |
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RU2191203C1 |
METHOD FOR OBTAINING GASOLINE FRACTIONS AND AROMATIC HYDROCARBONS | 2022 |
|
RU2794676C1 |
Authors
Dates
2025-05-29—Published
2024-12-24—Filed