FIELD: petroleum chemistry, synthesis of linear α-olefins C8-C18. SUBSTANCE: synthesis is carried out by ethylene oligomerization in the medium of aromatic hydrocarbon or haloid-containing hydrocarbon solvent at 70-120 C on the catalytic system. Catalytic system consists of zirconyl carboxylate of the formula ZrO(OCOR)nCl2-nR, R C3-C16-alkyl, n 1 or 2, ethylaluminiumsesquichloride or simple ether of the formula R2O where R C2-C5-alkyl, phenyl or tetrahydrofuran at the molar ratio 1:(10-30):(1-5). EFFECT: enhanced selectivity of process. 1 tbl
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| METHOD FOR PRODUCTION OF LINEAR α-OLEFINS C-C |
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- Khanmetov A.A.
- Azizov A.G.
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| METHOD OF COMBINED SYNTHESIS OF 1-[3-ETHYLTRICYCLO-(0)-DEC-7-ENE-2-YL]-1-ETHYL-1-CHLORALANE AND 1-[3-ETHYLTRICYCLO-(0)-DEC-6-ENE-2-YL]-1-ETHYL-1-CHLORALANE |
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|
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|
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