METHOD OF SYNTHESIS OF CIS-1,4-POLYBUTADIENE Russian patent published in 1995 - IPC

Abstract RU 2028308 C1

FIELD: industry of synthetic rubber. SUBSTANCE: polymerization of butadiene-1,3 is carried out in battery of at least three reactors arranged in-line in the medium of hydrocarbon solvent. Catalytic system consists of diiododichlorotitanium and triisobutylaluminium. Process is carried out in the presence of titanium tetrachloride which is added to the 2-d reactor and dialkylaluminium chloride or alkylaluminium sesquichloride added together at least with one of titanium compound at concentration 0.1-1.0 mole per 1.0 mole titanium compound. EFFECT: improved method of synthesis. 1 tbl

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RU 2 028 308 C1

Authors

Aksenov V.I.

Golovina N.A.

Byrikhin V.S.

Murachev V.B.

Gol'Berg I.P.

Byrikhin A.S.

Zaboristov V.N.

Rjakhovskij V.S.

Khlustikov V.I.

Dates

1995-02-09Published

1992-06-15Filed