PROCESS FOR PREPARING METHYL TERT-BUTYL ETHER Russian patent published in 1995 - IPC

Abstract RU 2029758 C1

FIELD: organic chemistry. SUBSTANCE: methyl tert-butyl ether is prepared by contacting an isobutylene-containing C₄- fraction and methanol in a liquid phase at elevated temperature in the presence of a sulfocationite catalyst in H-form in two reaction zones at a total methanol to isobutylene molar ratio of 0.90-0.99:1 by feeding the starting 85-95% C₄ fraction into the first reaction zone and the remaining amount into the second zone at maintaining 20-40 C and subsequently separating the reaction mixture and recovering the desired product. EFFECT: lower power consumption at the stage of recovery of methanol from the spent C₄-fraction and greater efficiency of the catalyst. 1 tbl

Similar patents RU2029758C1

Title	Year	Author	Number
PROCESS FOR PREPARING METHYL TERT-BUTYL ESTER	1991	Kapustin P.P. Kuz'Min V.Z. Kharitonov N.V. Shabalina L.N. Masternova T.V. Akopov O.D.	RU2032657C1
PROCESS FOR PREPARING METHYL TERT-BUTYL ETHER	1994	Kapustin P.P. Kuz'Min V.Z. Suchkov Ju.P. Makarov M.G.	RU2063397C1
PROCESS FOR PREPARING METHYL TERT-BUTYL ETHER	1994	Kapustin P.P. Vorozhejkin A.P. Rjazanov Ju.I. Gavrilov G.S. Ukhov N.I.	RU2063398C1
METHYL-TRET-BUTYL ESTER PRODUCTION PROCESS CONTROL METHOD	1992	Vorozhejkin A.P. Rjazanov Ju.I. Ukhov N.I. Gavrilov G.S. Kozhin N.I. Strjakhileva M.N. Kovalenko V.V. Khajrov R.A.	RU2060771C1
METHOD OF PRODUCING METHYL-TERT-BUTYL ETHER	1992	Galiev R.G. Sakhapov G.Z. Sharafeev Z.F. Khismatullin N.I. Shajdullin F.F. Kolontsov A.V. Gil'Mutdinov G.Z. Tul'Chinskij Eh.A. Kapustin P.P. Kiper A.I. Sosnovskaja L.B. Gershanov F.B.	RU2076860C1
METHOD FOR ISOLATION OF TERTIARY OLEFINS	1992	Gorshkov V.A. Pavlov S.Ju. Churkin V.N. Karpov I.P. Kurbatov V.A. Liakumovich A.G. Pavlova I.P. Bubnova I.A. Smirnov V.A.	RU2005710C1
METHOD OF METHYL-TERT-BUTYL ESTER SYNTHESIS	1991	Pavlov S.Ju. Gorshkov V.A. Strjakhileva M.N. Smirnov V.A. Churkin V.N. Kotel'Nikov N.G. Stoljarchuk V.I. Kazakov V.P. Gimbutas A.A. Njamunis Ju.V. Snjatkov A.F. Ter-Minas'Jan A.G.	RU2008304C1
PROCESS FOR SEPARATION OF TERTIARY OLEFINS	1992	Gorshkov V.A. Pavlov S.Ju. Kurbatov V.A. Liakumovich A.G. Churkin V.N. Karpov I.P. Pavlova I.P. Bubnova I.A. Titova L.F.	RU2005709C1
METHOD FOR PRODUCTION OF METHYL-TERT-BUTYL ETHER	1991	Strjakhileva M.N. Smirnov V.A. Pavlov S.Ju. Vavilov A.V. Gorshkov V.A. Stoljarchuk V.I. Kazakov V.P. Rjazanov Ju.I. Kozhin N.I. Gavrilov G.S. Ukhov N.I. Kuz'Menko V.V. Kovalenko V.V.	RU2030383C1
METHOD OF PREPARING ALKYL-TERT-ALKYL ETHERS	1992	Pavlov S.Ju. Gorshkov V.A. Pavlova I.P. Karpov I.P. Stoljarchuk V.I.	RU2068838C1

RU 2 029 758 C1

Authors

Kapustin P.P.

Prokudina T.M.

Vorozhejkin A.P.

Kozhin N.I.

Ukhov N.I.

Dates

1995-02-27—Published

1991-06-28—Filed