FIELD: processing of hydrogen sulfide-containing gases. SUBSTANCE: method for production of sulfur from hydrogen sulfide-containing gases consists in that hydrogen sulfide-containing gas in processed by Klaus method including high-temperature oxidation of initial gas, three-stage catalytic oxidation of obtained gas mixture to separate formed gas sulfur after thermal, first and second catalytic stages of gas mixture cooling and absorption of formed sulfur in the third catalytic stage to which gas mixture is fed with volumetric ratio of SO2/H2S = 0,1-0,4 and waste gas containing not more than 0.5 vol. of hydrogen sulfide is directed to the fourth catalytic stage. In so doing, the process in the fourth catalytic stage is effected, either, by direct oxidation of hydrogen sulfide with air oxygen and absorption of formed sulfur, or by chemisorption of hydrogen sulfide by metal oxides taken from group of oxides of zinc, iron and copper. EFFECT: increased yield of elementary sulfur up to 99.9% 9 cl, 1 dwg, 2 tbl
Title | Year | Author | Number |
---|---|---|---|
METHOD OF SULFUR PRODUCING | 1991 |
|
RU2022916C1 |
METHOD OF PREPARATION OF SORBENT FOR CLEANING GASES FROM HYDROGEN SULFIDE | 2004 |
|
RU2254916C1 |
METHOD FOR PROCESSING HYDROGEN SULPHIDE-CONTAINING GASES | 1989 |
|
RU2035209C1 |
PROCESS OF OXIDATING HYDROGEN SULFIDE | 2016 |
|
RU2632014C1 |
METHOD OF REMOVING SULFUR FROM HYDROGEN SULFIDE-CONTAINING GAS | 1999 |
|
RU2232128C2 |
METHOD OF SULFUR PRODUCTION FROM ACID GAS CONTAINING (17) | 1990 |
|
RU2072963C1 |
METHOD FOR AUTOMATICALLY CONTROLLING THE PRODUCTION OF ELEMENTAL SULPHUR | 0 |
|
SU1039874A1 |
HIGH-EFFICIENCY METHOD OF PRODUCING SULFUR FROM ACID GAS FLOW | 2005 |
|
RU2388524C2 |
METHOD FOR HIGH-EFFICIENCY EXTRACTION OF SULPHUR FROM ACIDIC GAS STREAM | 2005 |
|
RU2383385C2 |
METHOD OF PRODUCING SULPHUR FROM ACID GASES WITH LOW CONTENT OF HYDROGEN SULPHIDE | 2010 |
|
RU2430014C1 |
Authors
Dates
1995-07-25—Published
1992-01-23—Filed