PYRIMIDINE DERIVATIVES Russian patent published in 1995 - IPC

FIELD: organic chemistry. SUBSTANCE: products: fungicide compounds derivative of pyrimidinemethoxypropionate of the formula where any two groups K, L, M are nitrogen, the third group is -CH-; G H, halogen; X hydroxy-group, H, halogen, C₁-C₄-alkyl nonsubstituted or substituted with halogen, hydroxyl or cyano-group, C₂-C₄-alkenyl, C₂-C₄-alkynyl, trimethylsilyl-substituted C₂-C₄-alkynyl, C₂-C₄-alkenylhydroxy, C₂-C₄-alkynylhydroxy, phenyl, cyano, thiocyanato, nitro-group, NR′R″ where R′ and R″ are H, C₁-C₄-alkyl. group C₁-C₄-alkylcarbonylamino-, azido-group, C₁-C₄-alkoxy-, phenoxy-, benzylhydroxy-group, C₁-C₄-alkoxycarbonyl, C₁-C₄-alkoxycarbonylmethyl, C₁-C₄-alkanoylhydroxy, C₁-C₄-alkylsulfonylhydroxy, C₁-C₄-alkylthio, C₁-C₄-alkylsulfinyl, C₁-C₄-alkylsulfonyl, formyl, C₁-C₄-alkanoyl, hydroxymethyl-C₁-C₄-alkyl, carbamoyl, thiocarbamoyl, or the group ; Y halogen, C₁-C₄-alkyl, C₁-C₄-alkoxy, nitro, di-C₁-C₄-alkylamino-group, H, or X and Y when they are in ortho-position together with phenyl-ring to which they are bound and form naphthalene ring; A halogen, H, C₁-C₄-alkyl or C₁-C₄-alkoxy-group. Synthesized compounds were used in agriculture for struggle against fungous infections. EFFECT: improved method of synthesis. 7 tbl