FIELD: chemistry of polymers. SUBSTANCE: cis-1,4-polybutadiene and cis-1,4-butadiene- isoprene copolymer using Ziegler-Natt catalyst systems. Catalyst is complex preformed by reacting solvated salts of rare-earth elements (A) with organoaluminium compound (B) in the presence of conjugated diene (C) at A:B:C molar ratios of 1:(5-20):(0.5-50), and molecular weight regulator is dialkyl aluminium hydride. Polymers prepared by the claimed process have reduced plasticity and cold flow. EFFECT: more efficient preparation process. 2 cl, 1 tbl
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Authors
Dates
1999-03-10—Published
1997-03-11—Filed