FIELD: improved methods of production of acid fluorides of sulfonic acids. SUBSTANCE: acid fluorides of sulfonic acids are produced by treatment of corresponding acid chlorides with anhydrous hydrogen fluoride in presence of chromium-magnesium catalyst at temperature of 80-200 C. Invention products find wide application as biologically active compounds and as intermediate products for organic synthesis, particularly, for production of acid fluorides of perfluorated sulfonic acids by electrochemical fluorination. Proposed method excludes hydrolysis and use of fire-hazardous organic solvents with preserved high yield of desired products. EFFECT: higher efficiency. 1 tbl, 7 ex
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Authors
Dates
2002-06-20—Published
2001-02-27—Filed