CATALYST FOR ETHYLENE POLYMERIZATION BASED ON BIS-(IMINO)PYRIDYL COMPLEXES Russian patent published in 2002 - IPC

Abstract RU 2194056 C1

FIELD: organic chemistry, chemical technology, catalysts. SUBSTANCE: High-density polyethelene with different molecular and thermal indices is synthesized in suspension regimen of polymerization reaction at temperatures 70-80 C, under pressure 0.1-1.5 MPa by effect of novel 2,6-bis-(imino)pyridyl complexes of the formula: where M means Fe+2, Co+2; R1 means methyl group; R3 means hydrogen atom, methyl, ethyl or isopropyl group; R4 means hydrogen atom or methyl group; R2 means cycloalkyl group with carbon atom number 6, not less, and alkylalumoxane. Toluene, n-hexane, benzine and others are used as hydrocarbon solvents. Invention solves the problem of synthesis of novel homogeneous catalysts retaining activity at increased temperatures of polymerization reaction. EFFECT: improved properties of catalyst. 3 tbl, 22 ex

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RU 2 194 056 C1

Authors

Ivanchev S.S.

Tolstikov G.A.

Gabutdinov M.S.

Kudrjashov V.N.

Olejnik I.I.

Ivancheva N.I.

Badaev V.K.

Olejnik I.V.

Dates

2002-12-10Published

2001-09-25Filed