CATALYST AND A METHOD FOR PRODUCTION OF SYNTHESIS GAS VIA HYDROCARBON CONVERSION Russian patent published in 2002 - IPC

Abstract RU 2194572 C2

FIELD: gas fuel production and catalysts. SUBSTANCE: catalyst represents a lamellar hydrosilicate phase with stivensite-type structure of general formula (NixMe1-x)3Si4O10(OH)2•nH2O, wherein Me denotes one or several alkali-earth metals, x varies between 0.01 and 1, and n is less than 50, or metasilicate phase with enstatite-type structure of general formula (NixMe1-x)3SiO3, wherein Me, x, and n are as above, or hydroaluminosilicate phase with amesite-type structure of general formula (Ni1-x-yMexAly)3(Al3ySi2-3yO5)(OH)4•nH2O, wherein Me denotes one or several alkali-earth metals, x is below 0.8, y varies between 0.02 and 0.64, and n is less than 50, or hydroaluminosilicate phase with chlorite-type structure of general formula (Ni1-x-yMexAly)3(Al3ySi2-3yO5)(OH)4•nH2O,, wherein Me denotes one or several alkali-earth metals, x is below 0.8, y varies between 0.02 and 0.62, and n is less than 50, nickel-to-silicon atomic ratio ranging from 0.01 to 75. Production of synthesis gas from hydrocarbons is effected by bringing hydrocarbons into gas-phase interaction with an optionally nitrogen-diluted mixture of water and/or oxygen, and carbon dioxide in presence of above-indicated catalysts. Absence of silica phase in catalyst composition ensures process stability. EFFECT: increased activity and selectivity of catalyst. 6 cl, 1 tbl, 7 ex

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RU 2 194 572 C2

Authors

Jur'Eva T.M.

Itenberg I.Sh.

Kustova G.N.

Demeshkina M.P.

Bobrova I.I.

Zolotarskij I.A.

Minjukova T.P.

Parmon V.N.

Khasin A.A.

Dates

2002-12-20Published

2001-03-26Filed