Patenton — panteon of patents

(19)

RU

(11)

2 197 467

(13)

C2

(51)

IPC

(21) (22)

Application

2000127995/04, 2000-11-09

(24)

Start date

2000-11-09

(22)

Actual filing date

2000-11-09

(45)

Published

2003-01-27

(72)

Inventor

Bajguzina A.R.Shchadneva N.A.Kovtunenko I.A.Khusnutdinov R.I.Dzhemilev U.M.

(73)

Holder

Institut Neftekhimii I Kataliza An Rb I Unts Ran

METHOD OF PREPARING 1-CHLORO-3-ACETYL- AND 1-CHLORO-1,3-DIACETYLADAMANTANES Russian patent published in 2003 - IPC

Abstract RU 2197467 C2

FIELD: organic synthesis. SUBSTANCE: 1-chloro-3-acetyl- and 1-chloro-1,3- diacetyladamantanes useful as intermediates in synthesis of a series of 1,3- disubstituted and 1,3,5-trisubstituted adamantanes are prepared by chlorination of 1- acetyladamantane by carbon tetrachloride catalyzed by manganese complexes such as MnSO4, MnCl2, Mn(C17H35CO2)2 (stearate), Mn(OAc)2, Mn(acac)3, activated by nitrile ligands (CH3CN, CH3CH2CN, PhCN, CH2(CN)2) for 10-3 h at 200 C and molar ratio [Mn] /[RCN] /[1-acetyladamantane]/[CCl4] = 1:(2-4) : 1000:(1500-5000). Conversion of 1-acetyladamantane is ~ 100% and yield of desired products 98 and 92%, respectively. EFFECT: expanded synthetic possibilities in adamantine series. 1 tbl, 2 ex

Similar patents RU2197467C2

Title Year Author Number
METHOD OF SYNTHESIS OF 1-CHLOROADAMANTANE, 1- AND 4-CHLORODIAMANTANES 2000
  • Bajguzina A.R.
  • Shchadneva N.A.
  • Dodonova N.E.
  • Khusnutdinov R.I.
  • Dzhemilev U.M.
 RU2185364C1
METHOD OF PREPARING 1-CHLOROADAMANTAN-4-ON 2000
  • Dzhemilev U.M.
  • Bajguzina A.R.
  • Shchadneva N.A.
  • Khusnutdinov R.I.
 RU2197468C2
METHOD OF SYNTHESIS OF HEXACHLOROETHANE 2001
  • Dzhemilev U.M.
  • Khusnutdinov R.I.
  • Shchadneva N.A.
  • Bajguzina A.R.
 RU2185365C1
METHOD OF SYNTHESIS OF 1,3-DICHLOROADAMANTANE 2000
  • Khusnutdinov R.I.
  • Latypov V.N.
  • Shchadneva N.A.
  • Bajguzina A.R.
  • Dzhemilev U.M.
 RU2178401C2
METHOD OF PRODUCING 1-ACETYLADAMANTANE 2008
  • Dzhemilev Usein Memetovich
  • Khusnutdinov Ravil Ismagilovich
  • Shchadneva Nina Alekseevna
  • Mukhametshina Lilija Fagimovna
 RU2440326C2
METHOD OF PRODUCING 1-CHLORO-3-CYANOADAMANTANE 2009
  • Dzhemilev Usein Memetovich
  • Khusnutdinov Ravil Ismagilovich
  • Shchadneva Nina Alekseevna
  • Majakova Julija Jur'Evna
 RU2434848C2
METHOD FOR JOINT PRODUCTION OF E3,E8-DIMETHYL-TRANS-BICYCLO[4,4,0]DECANE AND E3,E9- DIMETHYL-TRANS-BICYCLO[4,4,0]DECANE 2000
  • Dzhemilev U.M.
  • Sadykov R.A.
  • Samokhina M.G.
 RU2188813C2
METHOD OF SYNTHESIS OF 1- AND 2-CHLOROADAMANTANE FROM 1- AND 2-ADAMANTANOL 2000
  • Khusnutdinov R.I.
  • Latypov V.N.
  • Shchadneva N.A.
  • Bajguzina A.R.
  • Dzhemilev U.M.
 RU2178400C2
PROCESS FOR PREPARING MIXTURE OF 1-CHLORO-AND 1,3- DICHLOROADAMANTANES 1996
  • Dzhemilev U.M.
  • Khusnutdinov R.I.
  • Shchadneva N.A.
  • Latypov V.N.
 RU2125551C1
PROCESS FOR PREPARING 1-CHLOROADAMANTANE 1996
  • Dzhemilev U.M.
  • Khusnutdinov R.I.
  • Shchadneva N.A.
  • Latypov V.N.
 RU2126784C1

RU 2 197 467 C2

Authors

Bajguzina A.R.

Shchadneva N.A.

Kovtunenko I.A.

Khusnutdinov R.I.

Dzhemilev U.M.

Dates

2003-01-27—Published

2000-11-09—Filed

read Similar patents