PROCESS FOR PREPARING 1-CHLOROADAMANTANE Russian patent published in 1999 - IPC

Abstract RU 2126784 C1

FIELD: organic chemistry. SUBSTANCE: adamantane is chlorinated with carbon tetrachloride and rhodium catalysts such as Rh(PRh3)3Cl2, [Rh(HBD)Cl]2 wherein NBD is norbornadiene, [Rh(CO)2Cl]2, Rh4(CO)12 at 150-200 C for 5 h at adamantane; rhodium salt: carbon tetrachloride molar ratio of 1:(0.005-0.01): (1.5-5). Yield of the final product is as high as 89-92% at complete adamantane conversion. EFFECT: more efficient preparation process. 2 cl, 23 ex, 1 tbl

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RU 2 126 784 C1

Authors

Dzhemilev U.M.

Khusnutdinov R.I.

Shchadneva N.A.

Latypov V.N.

Dates

1999-02-27Published

1996-12-05Filed