FIELD: polymer materials. SUBSTANCE: invention relates to powder coating compositions based on solid epoxide resins and carboxylcontaining polyester resins prepared using polyethylene terephthalate waste, which are used for corrosion-protective and ornamental coatings for metals and metalware. Composition is prepared by alkoholysis of secondary polyethylene terephthalate (household storage containers) with polyatomic alcohol and esterification of resulting hydroxyl-containing polyester with phthalic anhydride distillation waste at molar ratio of phthalic anhydride to hydroxylcontaining polyester (0.31-0.35):1 to give solid carboxyl-containing polyester resin. The latter (30-56%) is then mixed with solid 4,4'-isopropylidene epoxide resin (28-54%) in presence of zinc oxide (3-5%) as hardening catalyst, vinyline (1-2%) as flow property regulator, pigment (1.5-9%), and ferroalloy production waste (6- 9%) as filler, said ferroalloy production waste being more particularly ferrovanadium slime or silicate dust of ferrosilicium. Resulting mixture is homogenized and disintegrated. EFFECT: extended source of starting materials, utilized household and industrial wastes, reduced production expenses, and improved physicochemical characteristics of coatings. 3 cl, 5 tbl
Title | Year | Author | Number |
---|---|---|---|
POWDER PAINT FOR COATINGS | 1998 |
|
RU2178436C2 |
METHOD OF PRODUCING POLYMER COMPOSITIONS USING POLYETHYLENE TEREPHTHALATE WASTE TREATMENT STEP | 2011 |
|
RU2496805C2 |
METHOD OF PRODUCING POWDER COMPOSITION FOR COATINGS | 0 |
|
SU1495349A1 |
METHOD FOR PRODUCTION OF POLYESTER-POLYOLS AND RIGID FOAMED PLASTICS BASED THEREON | 2003 |
|
RU2236422C1 |
METHOD OF SYNTHESIS OF PHTHALONITRILE | 2000 |
|
RU2203270C2 |
METHOD FOR PREPARING ALKYD OLIGOMERS AND ALKYD LACQUER CONTAINING ALKYD OLIGOMER | 2005 |
|
RU2285705C1 |
UNDERCOAT COMPOSITION FOR COATINGS | 2003 |
|
RU2252236C1 |
METHOD FOR PREPARING ALKYD OLIGOMERS | 2001 |
|
RU2209818C1 |
POLYMER PRODUCTION METHOD | 2008 |
|
RU2494117C2 |
POWDER-LIKE EPOXY COMPOSITION FOR COATINGS | 1994 |
|
RU2129137C1 |
Authors
Dates
2003-03-10—Published
2000-06-07—Filed