FIELD: non-iron metallurgy, in particular gallium refining.
SUBSTANCE: crude gallium is converted to highly volatile gallium(I) oxide Ga2O by metal heating in presence of gallium(III) oxide Ga2O3 at 500-7000C in vacuum to provide a slop. Highly volatile gallium(I) oxide Ga2O is fed into disproportionation zone under the same conditions followed by disproportionation to form metal gallium and gallium(III) oxide Ga2O3 at 700-9000C Obtained slop is recycled to reuse by addition to starting crude gallium.
EFFECT: purified gallium with decreased content of Sn, Fe, Al, Si, Ni impurities; reduced waste; and low cost process.
4 tbl, 1 ex
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Authors
Dates
2005-02-20—Published
2003-02-04—Filed