FIELD: hydrometallurgy; reprocessing of molybdenum production wastes.
SUBSTANCE: the invention is pertaining to the field of hydrometallurgy, in particular, to a waste products processing. The wastes of molybdenum production are treated with mineral acids, separate the acid molybdenum-containing solution or use initial acid molybdenum-containing solution (waste products). Then conduct injection in it of a ferrous reactant, an additive of an alkaline reactant, aged pulp produced at stirring, filtration, flushing out and a drying. The last stage is calcination of ferromolybdate, which is conducted in two phases. At the first phase the calcination conduct at the temperature of 550-640°C within 1-2 hours, and then at the second phase - at the temperature of 870-950°C with simultaneous blowing by air at its consumption of 10-34 l/g·hours within 0.5-2.5 hours. The technical result of the invention is production of: ferromolybdates with the low contents of sulfur; a free from admixtures (S, W, Fe, etc.) molybdenum oxide (MoO3) suitable for production of high-grade molybdenum-containing products; cost reduction of pure molybdenum-containing product.
EFFECT: the invention ensures production of: ferromolybdates with the low contents of sulfur; a free from admixtures (S, W, Fe, etc) molybdenum oxide (MoO3) suitable for production of high-grade molybdenum-containing products; cost reduction of pure molybdenum-containing product.
1 tbl
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR PREPARING MOLYBDENITE PRODUCT | 2001 |
|
RU2213058C2 |
METHOD OF EXTRACTION OF MOLYBDENUM FROM THE ACID SOLUTIONS | 2004 |
|
RU2280088C2 |
METHOD OF PRODUCTION OF MOLYBDENUM TRIOXIDE AND THE DEVICE FOR THE METHOD REALIZATION | 2005 |
|
RU2312067C2 |
REGENERATION METHOD OF MOLYBDENUM FROM WASTE SOLUTION FOR ETCHING OF MOLYBDENUM CORE IN MANUFACTURING OF LIGHT BULBS AND ELECTRONIC DEVICES AND INSTALLATION FOR ITS IMPLEMENTATION | 2008 |
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METHOD FOR PROCESSING SPENT MOLYBDENUM-ALUMINIUM-CONTAINING CATALYST | 2017 |
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RU2645825C1 |
LOW-FLUORINE MANGANESE CONCENTRATE | 2001 |
|
RU2201399C1 |
CHARGE AND METHOD FOR ALUMINOTHERMIC PRODUCTION OF FERROMOLYBDENUM USING IT | 2012 |
|
RU2506338C1 |
METHOD OF PROCESSING MOLYBDENUM-CONTAINING RAW MATERIAL | 2005 |
|
RU2281914C1 |
SODIUM DYHYDROPYROPHOSPHATE PRODUCTION PROCESS | 2001 |
|
RU2181340C1 |
PROCESS FOR TREATING PRODUCTS CONTAINING MOLYBDENUM TRIOXIDE | 1991 |
|
RU2020174C1 |
Authors
Dates
2005-09-27—Published
2004-04-06—Filed