METHOD FOR PREPARING 1-(1-METHYL-2-(3,4-FULLERO[60]-PYRROLIDINYL))-1H-1,2,4-TRIAZOLE Russian patent published in 2006 - IPC C07D403/04 

Abstract RU 2283310 C1

FIELD: organic chemistry, chemical technology.

SUBSTANCE: invention relates to a method for synthesis of 1-91-methyl-2-(3,4-fullero[60]-pyrrolidinyl))-1H-1,2,4-triazole of the general formula (1): Method involves interaction of fullerene[60] with N-[(1,2,4-triazol-1-yl)methyl]-N,N-dimethylamine of the general formula: (R-CH2-N-(CH3)2 wherein R means taken in the mole ratio C60 : R-CH2-N-(CH3)2 = 0.01:(0.01-0.011) in the presence of Cp2TiCl2 as a catalyst taken in the amount 15-25 mole% relatively to fullerene[60], in argon atmosphere, in toluene medium as a solvent at temperature 140-160°C for 2-4 h. The end substance is prepared with the yield 78-86%. Compound of the formula (1) can be used as chelating agent, sorbent, biologically active compound and in the development of novel materials with required electronic, magnetic and optical properties.

EFFECT: improved method of synthesis.

1 tbl, 1 ex

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RU 2 283 310 C1

Authors

Dzhemilev Usein Memetovich

Ibragimov Askhat Gabdrakhmanovich

D'Jakonov Vladimir Anatol'Evich

Tuktarov Ajrat Ramilevich

Salamatina Tat'Jana Petrovna

Golikova Majja Timofeevna

Dates

2006-09-10Published

2005-04-01Filed