FIELD: organic chemistry, chemical technology.
SUBSTANCE: invention describes a novel method for synthesis of functionally substituted fullerenes of the general formula (I): Method involves interaction of fullerene[60] with 1H-1,2,3-benzotriazol-1-N,N-dimethylmethaneamine in the presence of Cp2TiCl2 as a catalyst in argon atmosphere, in toluene medium, at temperature 140-160°C for 2-4 h. The yield of the end product is 68-89%. Proposed compounds can be used as chelate compounds, sorbents, biologically active compounds and in the development of material with required electronic, magnetic and optical properties.
EFFECT: improved method of synthesis, valuable properties of compounds.
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Authors
Dates
2007-01-10—Published
2005-04-11—Filed