FIELD: organic chemistry, chemical technology.
SUBSTANCE: invention relates to a method for synthesis of novel additive poly-(5-trimethylsilylnorborn-2-ene) that can be used in different fields of industry and, in particular, in processes for separation of gases. Additive polymer no containing double bonds in the main chain, namely poly-(5-trimethylsilylnorborn-2-ene) corresponds to the following formula: , wherein n = 170-2000 (polymerization degree), value of average-weight molecular mass Mw = (2-40) x 104 g/mole and polydispersity index Mw/MN = 1.5-3.0. Proposed polymer is used in a method for membrane separation of gaseous mixtures with the super-high coefficient of gas permeability.
EFFECT: improved separating method, valuable properties of polymer.
2 cl, 2 dwg, 3 tbl, 10 ex
Title | Year | Author | Number |
---|---|---|---|
MONO- OR DISILICON-SUBSTITUTED TRICYCLONONENE, ADDITIVE POLY(MONO- OR DISILICON-SUBSTITUTED TRICYCLONONENE) AND METHOD OF SEPARATION OF GAS MIXTURES BY MEANS OF BASED ON IT MEMBRANES | 2009 |
|
RU2410397C1 |
ADDITIVE POLY(3-TRI(N-ALKOXY)SILYLTRICYCLO[4.2.1.0]NON-7-ENE), SYNTHESIS METHOD THEREOF AND METHOD FOR SEPARATION OF GASEOUS HYDROCARBONS USING MEMBRANE BASED THEREOF | 2018 |
|
RU2685429C1 |
ADDITIVE COPOLYMER 3,3,4-TRIS(TRIMETHYLSILYL)TRICYCLONONENE-7 AND 3-TRIMETHYLSILYLTRICYCLONONENE-7, METHOD OF ITS PRODUCTION AND METHOD FOR SEPARATING GAS MIXTURES WITH ITS APPLICATION | 2016 |
|
RU2634724C2 |
ADDITIVE POLY(MONO(TRIMETHYLGERMYL)-SUBSTITUTED TRICYCLONONENE), MONOMER FOR OBTAINING THEREOF AND METHOD OF SEPARATING GAS MIXTURES BASED ON ADDITIVE POLY(MONO(TRIMETHYLGERMYL)-SUBSTITUTED TRICYCLONONENE) | 2012 |
|
RU2522555C2 |
METHOD FOR SEPARATING CO-CONTAINING GAS MIXTURES | 2023 |
|
RU2807750C1 |
METATHESIS POLY(3-TRIALKOXYSILYLTRICYCLO[4.2.1.0]NON-7-ENE), A METHOD FOR PRODUCTION THEREOF AND A METHOD OF SEPARATING HYDROCARBON GASES USING | 2018 |
|
RU2697201C1 |
COMPOSITE MEMBRANE ON BASIS OF HIGHLY POROUS VITREOUS POLYMERS | 2012 |
|
RU2491983C1 |
BASED ON POLY(HEXAFLUOROPROPYLENE) MEMBRANE AND METHOD OF GASES SEPARATING USING IT | 2015 |
|
RU2606613C2 |
METHOD FOR PRODUCING AN ADDITIVE POLYMER BASED ON DICYCLOPENTADIENE (EMBODIMENTS) | 2018 |
|
RU2669562C1 |
HIGH-TEMPERATURE GAS-SEPARATING MEMBRANE BASED ON POLYNAPHTOYLENEBENZIMIDAZOLE AND METHOD FOR ITS PRODUCTION | 2021 |
|
RU2802750C2 |
Authors
Dates
2007-04-10—Published
2005-11-25—Filed