FIELD: chemistry.
SUBSTANCE: invention relates to additive poly(mono(trimethylgermyl)-substituted tricyclononene) of the general structural formula: , where n=300-2400 (polymerisation degree).A value of average weight molecular weight Mw of a polymer constitutes (7.1-57)·104 g/mol and a polydispersity index Mw/Mn constitutes 1.9-2.6. Also claimed are: a monomer for obtaining poly(mono(trimethylgermyl)-substituted tricyclononene) and a method of membrane separation of gas mixtures.
EFFECT: invention makes it possible to increase a coefficient of gas-permeability and selectivity of polymer-based membranes.
3 cl, 2 tbl, 3 ex, 4 dwg
Title | Year | Author | Number |
---|---|---|---|
MONO- OR DISILICON-SUBSTITUTED TRICYCLONONENE, ADDITIVE POLY(MONO- OR DISILICON-SUBSTITUTED TRICYCLONONENE) AND METHOD OF SEPARATION OF GAS MIXTURES BY MEANS OF BASED ON IT MEMBRANES | 2009 |
|
RU2410397C1 |
ADDITIVE COPOLYMER 3,3,4-TRIS(TRIMETHYLSILYL)TRICYCLONONENE-7 AND 3-TRIMETHYLSILYLTRICYCLONONENE-7, METHOD OF ITS PRODUCTION AND METHOD FOR SEPARATING GAS MIXTURES WITH ITS APPLICATION | 2016 |
|
RU2634724C2 |
ADDITIVE POLY-(5-TRIMETHYLSILYLNORBORN-2-ENE) AND METHOD FOR SEPARATING GASEOUS MIXTURES BY MEMBRANE BASED ON THEREOF | 2005 |
|
RU2296773C1 |
ADDITIVE POLY(3-TRI(N-ALKOXY)SILYLTRICYCLO[4.2.1.0]NON-7-ENE), SYNTHESIS METHOD THEREOF AND METHOD FOR SEPARATION OF GASEOUS HYDROCARBONS USING MEMBRANE BASED THEREOF | 2018 |
|
RU2685429C1 |
METATHESIS POLY(3-TRIALKOXYSILYLTRICYCLO[4.2.1.0]NON-7-ENE), A METHOD FOR PRODUCTION THEREOF AND A METHOD OF SEPARATING HYDROCARBON GASES USING | 2018 |
|
RU2697201C1 |
METHOD OF OBTAINING ADDITIVE POLYMERS BASED ON NORBORNENE CONTAINING DOUBLE BOND IN SUBSTITUENT | 2018 |
|
RU2671564C1 |
METHOD FOR PRODUCING AN ADDITIVE POLYMER BASED ON DICYCLOPENTADIENE (EMBODIMENTS) | 2018 |
|
RU2669562C1 |
METHOD OF ADDITIVE POLYMERIZATION OF NORBORNEN AND ITS DERIVATIVES | 2015 |
|
RU2626745C2 |
SINGLE-COMPONENT CATALYST FOR ADDITIVE POLYMERIZATION OF CYCLOOLEFIN, METHOD OF PRODUCING HOMOPOLYMER (VARIANTS) AND METHOD OF PRODUCING BLOCK COPOLYMER IN ITS PRESENCE | 2023 |
|
RU2812130C1 |
METHOD OF PRODUCING ADDITIVE POLYMERS BASED ON NORBORNENE (EMBODIMENTS) | 2021 |
|
RU2768465C1 |
Authors
Dates
2014-07-20—Published
2012-03-30—Filed