FIELD: organic chemistry.
SUBSTANCE: claimed method includes reaction of C60-fullerene with dipiperidine methane in presence of Cp2TiCl2 as catalyst in toluene medium at room temperature (approximately 20°C) for 15-25 hours. Yield of target product is 70-90 %. Compound of present invention is useful as chelating agent, sorbent, biologically active compound and for production of new materials with desired electronic, magnetic and optical properties. .
EFFECT: new compound; method of increased yield and selectivity.
1 tbl
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR PREPARING 8-ETHYL-6,7-FULLERO[60]-3-OXA-8-AZABICYCLO[3.2.1]OCTANE | 2006 |
|
RU2315047C1 |
METHOD FOR PREPARING 1-(2,7-OCTADIENYL)-2,5-DIMETHYL-3,4-FULLERO[60]PYRROLIDINE | 2006 |
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RU2315038C1 |
METHOD OF PRODUCING 1-(2-PROPENYL)-2,5-DIMETHYL-3,4-FULLERO[60]PYRROLIDINE | 2006 |
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METHOD FOR PRODUCTION OF N,N,1-TRIMETHYL-2-(3,4-FULLERO[60])PYRROLIDINE AMINE | 2005 |
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RU2283834C1 |
METHOD FOR PREPARING 1-(1-METHYL-2-(3,4-FULLERO[60]-PYRROLIDINYL))-1H-1,2,4-TRIAZOLE | 2005 |
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METHOD FOR PREPARING 2-(1-METHYL-2-(3,4-FULLERO[60]-PYRROLIDINYL)PHENOL | 2005 |
|
RU2283302C1 |
METHOD FOR PRODUCTION OF 5-METHYL-2,3-FULLERO[60]PIPERAZINE | 2006 |
|
RU2307832C1 |
METHOD FOR PREPARING 1-(4-QUINOLINAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2313521C1 |
METHOD FOR PREPARING 1-(N,N-DIPHENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
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RU2309941C1 |
METHOD FOR PREPARING 1-(N,N-DIPROP-2-ENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
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RU2309939C1 |
Authors
Dates
2007-10-10—Published
2006-05-06—Filed