FIELD: organic chemistry, chemical technology.
SUBSTANCE: invention relates to a method for synthesis of 1-(2,7-octadienyl)-2,5-dimethyl-3,4-fullero[60]pyrrolidine of the general formula (1): 
. Method involves interaction of fullerene[60] with N,N-diethyl-2,7-octadiene-1-ylamine taken in the mole ratio fullerene-C60 : N,N-diethyl-2,7-octadiene-1-ylamine = 0.01:(0.011-0.012) in the presence of Cp2TiCl2 as a catalyst taken in the amount 15-25 mole% with respect to fullerene[60], in toluene medium as a solvent, at temperature 150-170°C for 2-4 h. Method provides preparing the end substance with the yield 65-86%.
EFFECT: improved method of synthesis.
1 tbl, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD FOR PRODUCTION OF 8-1-PIPERIDINYLMETHYL)-6,7-FULLERO[60]-8-AZABICYCLO[3.2.1.]OCTANE | 2006 |
|
RU2307836C1 |
| METHOD OF PRODUCING 1-(2-PROPENYL)-2,5-DIMETHYL-3,4-FULLERO[60]PYRROLIDINE | 2006 |
|
RU2372334C2 |
| METHOD FOR PREPARING 1-(1-METHYL-2-(3,4-FULLERO[60]-PYRROLIDINYL))-1H-1,2,4-TRIAZOLE | 2005 |
|
RU2283310C1 |
| METHOD FOR PREPARING 2-(1-METHYL-2-(3,4-FULLERO[60]-PYRROLIDINYL)PHENOL | 2005 |
|
RU2283302C1 |
| METHOD FOR PRODUCTION OF N,N,1-TRIMETHYL-2-(3,4-FULLERO[60])PYRROLIDINE AMINE | 2005 |
|
RU2283834C1 |
| METHOD FOR PREPARING 8-ETHYL-6,7-FULLERO[60]-3-OXA-8-AZABICYCLO[3.2.1]OCTANE | 2006 |
|
RU2315047C1 |
| METHOD FOR PREPARING 1-PHENYL-2,5-DIALKYL-3,4-FULLERO[60]PHOSPHOLANES | 2006 |
|
RU2310660C1 |
| METHOD FOR PREPARING 1-(N,N-DIPHENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309941C1 |
| METHOD FOR PREPARING 1-(N,N-DIPROP-2-ENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309939C1 |
| METHOD FOR PRODUCTION OF 5-METHYL-2,3-FULLERO[60]PIPERAZINE | 2006 |
|
RU2307832C1 |
