FIELD: organic chemistry, chemical technology.
SUBSTANCE: invention relates to methods for synthesis of (-γ)-propylsilanes substituted at position 3. Invention proposes initial charging a platinum-containing catalyst and 10-30 wt.-% of reaction mass from previous step or vat residues after isolation of the end product from previous step into reactor. Then the mixture is heated to temperature 65°C and silane hydride and allyl chloride are dosed maintaining the mole ratio silane hydride and allyl chloride in the reaction mass = (1.0-1.2):1. Invention provides development of method allowing significant decreasing consumption of catalyst, declining formation of by-side products and enhancing the effectiveness of technological process.
EFFECT: improved method of synthesis.
3 cl, 1 tbl, 10 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF OBTAINING OCTYLTRIETHOXYSYLANE | 2007 |
|
RU2352574C1 |
METHOD FOR PREPARING ALKYLSILANES | 2005 |
|
RU2277538C1 |
METHOD FOR PREPARING PROPYLSILANE FUNCTIONALIZED AT POSITION 3 | 2002 |
|
RU2275375C2 |
PHENOL-ORGANOSILOXANES AND METHOD FOR PRODUCTION THEREOF | 2012 |
|
RU2487901C1 |
METHOD FOR PREPARING ALKYL SILANES | 2001 |
|
RU2219126C2 |
METHOD OF PREPARING HYDROSILYLATION REACTION CATALYST | 2001 |
|
RU2220769C2 |
METHOD OF OBTAINING CATALYSTS OF WATER-ALKALI DEHYDROCHLORINATION | 2006 |
|
RU2341329C2 |
WATER-ALKALI DEHYDROCHLORINATION CATALYST PREPARATION METHOD | 2003 |
|
RU2247601C2 |
METHOD OF PREPARING CATALYSTS FOR AQUEOUS-ALKALI DEHYDROCHLORINATION OF POLYCHLOROALKANES | 1999 |
|
RU2174441C2 |
METHOD FOR PREPARATION OF BASE FOR SYNTHETIC LUBRICATING OIL | 0 |
|
SU1723101A1 |
Authors
Dates
2008-03-27—Published
2007-01-09—Filed