FIELD: organic chemistry.
SUBSTANCE: invention refers to enhanced method of propane and/or butanes flow separation from original hydrocarbons containing alkylmercaptan impurities by means of fractional distillation resulted in liquid phase and separated flow from column head at pressure providing that separated flow from column head containing propane and/or butanes has temperature within 50 to 100°C, including (i) addition to specified origin hydrocarbons an amount of oxygen sufficient for mercaptan oxidation, (ii) fractional distillation of produced mixture containing at least one catalyst layer oxidising mercaptans to sulphur compounds with higher boiling temperatures and (iii) separation of sulphur compounds with higher boiling temperatures as portion of distillation liquid phase.
EFFECT: improved method of propane and/or butanes flow separation from of original hydrocarbons by means of fractional distillation resulted in liquid phase and separated flow.
8 cl, 2 tbl, 1 dwg, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF HYDRODESULPHURISATION WITH CHOSEN LIQUID RECYCLE TO REDUCE FORMATION OF RECOMBINANT MERCAPTANS | 2011 |
|
RU2539600C2 |
| IMPROVED METHOD OF HYDRODESULPHURISATION USING CHOSEN FLOWS OF NAPHTHA | 2004 |
|
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| PROCESS OF DESULFURIZATION OF CATALYTICALLY CRACKED GASOLINE-LIGROIN FRACTION (OPTIONS) | 2002 |
|
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| METHOD OF SIMULTANEOUS HYDROFINING AND FRACTIONING OF HYDROCARBON FLOWS IN LIGHT NAPHTHA | 2004 |
|
RU2330874C2 |
| GASOLINE DESULFURIZATION PROCESS | 1996 |
|
RU2149172C1 |
| METHOD OF TREATING STREAMS OF LIGHT NAPHTA HYDROCARBONS | 2003 |
|
RU2327731C2 |
| GASOLINE WITH SULFUR AND MERCAPTANS SMALL AMOUNT PRODUCTION METHOD | 2014 |
|
RU2665701C2 |
| PETROL PROCESSING METHOD | 2017 |
|
RU2731566C2 |
| PROCESS OF HYDRODECULFURIZATION OF OIL FEEDSTOCK AND PROCESS OF HYDRODESULFURIZATION OF CRACKED NAPHTHA (OPTIONS) | 2000 |
|
RU2241021C2 |
| LOWER OLEFIN OLIGOMERIZATION PROCESS | 1998 |
|
RU2135547C1 |
