FIELD: chemistry.
SUBSTANCE: invention relates to new substituted 4-hydroxy-6-nitro-2-phenylindole of general formula I where R1 means H, alkyl, R2 means H, and/or alcoxyl, and/or halogen, n equals 0-5, except for 4-hydroxy-6-nitro-2-phenilindole. Compounds I including 4-hydroxy-6-nitro-2-phenilindole have fungicidal activity, which allows their use as fungicidal agents. Compounds are obtained from O-(3,5-dinitrophenyl)ketoxims of general formula III where R1, R2 and n have the aforesaid values, their procession with hydrazine hydrate in aliphatic alcohol with boiling in presence of iron salt and activated coal, with obtaining corresponding substituted O-(3-amino-5-nitrophenyl)ketoxims of general formula IV which are subjected to intramolecular cyclisation in mixture of acid and aliphatic alcohol at temperature of mixture boiling.
EFFECT: obtaining 4-hydroxy-6-nitro-2-phenylindole and compositions on its basis, which possess fungicidal activity.
5 cl, 1 tbl, 9 ex
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Authors
Dates
2008-09-20—Published
2007-03-27—Filed