FIELD: chemistry.
SUBSTANCE: method lies in enantioselective oxidation with organic peroxides of (S)-5-methoxy-2-((4-methoxy-3,5-dimethylpyridin-2-yl)methylthio)-1H-benzo[d]imidazole in presence of catalytic complex of titanium (IV) with simultaneously two chiral ligands: chiral diol (preferably D-diethyltartrate) and chiral amine (preferably N,N-dimethyl-(R)-1-phenylethylamin).
EFFECT: increase of target product or its salt output.
1 cl, 1 dwg, 4 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF OBTAINING OPTICALLY ACTIVE 5-METHOXY-2-((4-METHOXY-3,5-DIMETHYLPYRIDIN-2-YL)METHYLSULFINYL)-1H-BENZO[d]IMIDAZOLE | 2007 |
|
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0 |
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Authors
Dates
2008-11-27—Published
2007-04-12—Filed