FIELD: chemistry.
SUBSTANCE: invention refers to electrochemical method of primary and secondary alcohol oxidation to related carbonyl compounds including preparation of mother solution at room temperature. Then salt 2,2,6,6-tetramethylpiperidine hydrochloride of general formula is added to electrolyte solution consisting of oxidised alcohol, water, methylene chloride, sodium chloride and sodium sulphate with electrolysis on platinum electrodes at current strength 1.5 A and temperature 20-25°C.
EFFECT: higher technological effectiveness of process combined with reduced time for producing high-yield end product.
2 ex
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0 |
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Authors
Dates
2009-04-10—Published
2007-07-31—Filed