METHOD OF ALCOHOL OXIDATION TO CARBONYL COMPOUNDS Russian patent published in 2009 - IPC C25B3/02 C07C45/29 C07C47/54 C07C49/603 

Abstract RU 2351693 C1

FIELD: chemistry.

SUBSTANCE: invention refers to electrochemical method of primary and secondary alcohol oxidation to related carbonyl compounds including preparation of mother solution at room temperature. Then salt 2,2,6,6-tetramethylpiperidine hydrochloride of general formula is added to electrolyte solution consisting of oxidised alcohol, water, methylene chloride, sodium chloride and sodium sulphate with electrolysis on platinum electrodes at current strength 1.5 A and temperature 20-25°C.

EFFECT: higher technological effectiveness of process combined with reduced time for producing high-yield end product.

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RU 2 351 693 C1

Authors

Kashparov Ivan Igorevich

Kashparova Vera Pavlovna

Zhukova Irina Jur'Evna

Kagan Efim Sholomovich

Dates

2009-04-10Published

2007-07-31Filed