FIELD: chemistry.
SUBSTANCE: method involves preparation of a reaction mixture at room temperature consisting of the alcohol to be oxidised, sodium bicarbonate, an organic solvent and a nitroxyl radical. Electrolysis is carried out on platinum electrodes with current of 1 A and temperature of 20-25°C. Potassium iodide is added to the reaction mixture. The organic solvent used is dichloromethane and the nitroxyl radical used is 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxyl of formula: 
with ratio of alcohol to nitroxyl radical equal to 10:1.
EFFECT: invention ensures high output of end products a within short period of time and less expenses on electricity using a high-technology method.
2 ex
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