FIELD: chemistry.
SUBSTANCE: catalysts for preparation of biofuel by reesterification of vegetable oil with alcohol represent composition based on hexaaluminate (MAl12O19) having magnetoplumbite or β-Al2O3 whereat: M - Ba or Sr, or La, or having spinel structure (MR2O4) whereat: M - Ca or Sr, or Ba, whereat R contains Y or La, or composition based on MgO+R2O3+solid solution R2-xMgxO3 with hexagonal structure whereat R contains Y or La, x=0.05÷0.12. The method for catalysts preparation includes precipitation of mixed solution of M and Al nitrates whereat M contains Ba or Sr, or La at constant values of pH 7.5-8.0 and temperature with water solution of NH4HCO3, or precipitation of mixed solution of M and R whereat M = Ca or Sr, or Ba, R contains Y or La at constant values pH equal to 9.9÷11.9 and temperature with water solution of KOH, or precipitation mixed solution of Mg and R nitrates at constant values of pH equal to 9.0-9.5 and temperature with water solution of KOH followed with stages of filtration, washing, drying and calcination. The method of biofuel preparation involves the reesterification of vegetable oil with alcohol implemented in the presence of the catalyst described above.
EFFECT: high level of the vegetable oil conversion.
13 cl, 1 tbl, 18 ex
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Authors
Dates
2009-09-10—Published
2008-04-14—Filed