FIELD: chemistry.
SUBSTANCE: invention relates to electrochemical synthesis of refractory tungsten compounds and can be used for producing nanodispersed hard-alloy compositions based on tungsten carbide and cobalt, with high melting points, hardness, strength, elasticity, chemical inertness. A melt, containing, mol %: lithium tungstate 30.0 to 40.0, cobalt tungstate 2.5 to 5.0, lithium carbonate 15.0 to 20.0, sodium tungstate - the rest, undergoes electrolysis in open cells in galvanostatic mode with cathode current density ranging from 2.5 to 7.5 A/cm2.
EFFECT: obtaining power with particles size ranging from 50 to 500 nm, doubling rate of synthesis of desired product, simplification of the process.
3 ex
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Authors
Dates
2009-11-10—Published
2008-08-04—Filed