FIELD: chemistry.
SUBSTANCE: invention relates to heat-resistant nonmetallic materials and can be used to make effective protective coatings of heating elements based on lanthanum chromite working in an air atmosphere. The invention involves use of a heat-resistant mixture composed of lanthanum chromite, frits from oxide phases and aluminoborosilicate glass with the following ratio of ingredients, in wt %: lanthanum chromite 32-44, frit 43-48, aluminoborosilicate glass 13-20. The frit from oxide phases contains the following components, in wt %: yttrium oxide Y2O3 63-65, aluminium-magnesium spinel MgAl2O4 13-21, lanthanum aluminate LaAl11O18 6-13, mullite Al6Si2O13 6-13, aluminoborosilicate glass SiO2 53-55, CaO 18-20, Al2O3 13-15, B2O3 9-11, MgO 2-4. The multicomponent material for protective coatings obtained from the mixture contains crystalline phases and a glass phase in the following ratio, in wt %: LaCrO3 29-42, Y2O3 30-31, MgAl2O4 6-8, LaAl11O18 3-5, Al6Si2O13 3-5, aluminoborosilicate glass phase 16-22.
EFFECT: fire-resistant mixture and multicomponent material provides strong adhesion of protective coatings to the surface of heating elements based on lanthanum chromite, prevention of crack formation and flaking of protective coatings during thermal cycles, longer life of heating elements with the protective coating.
2 cl, 7 ex, 4 tbl, 1 dwg
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Authors
Dates
2010-05-20—Published
2009-02-27—Filed