FIELD: chemistry.
SUBSTANCE: method involves reaction of bisamine with 3-fold excess acetylene in the presence of a vanadyl acetylacetonate (VO(acac)2) catalyst in an argon atmosphere at temperature 70°C and atmospheric pressure for 3 hours, followed by addition of diisobutylaluminium hydride and stirring the reaction mixture for 4-6 hours at room temperature. The method enables to obtain N1,N1,N4,N4-tetramethyl-2-butene-1,4-diamine from available reagents with quantitative output of (82-97%).
EFFECT: high output of end product.
1 tbl, 3 dwg, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PRODUCING N,N,N,N-TETRAMETHYL-2-BUTYNE-1,4-DIAMINE | 2010 |
|
RU2448951C2 |
| METHOD OF PRODUCING N,N,N,N-TETRAMETHYL-2-BUTYNE-1,4-DIAMINE | 2008 |
|
RU2408572C2 |
| METHOD OF PRODUCING N,N,N,N-TETRAMETHYLALKADIYNEDIAMINES | 2007 |
|
RU2373189C2 |
| METHOD OF PRODUCING N,N-DIMETHYL-3-PHENYL-2-PROPYNE-1-AMINE | 2007 |
|
RU2349579C1 |
| N,N-DIMETHYL-N-(4-QUINOLINENYLMETHYL)AMINE SYNTHESIS METHOD | 2008 |
|
RU2404165C2 |
| METHOD OF PRODUCING N,N,N,N-TETRAMETHYLBUTANE DITHIOAMIDE | 2009 |
|
RU2433996C2 |
| CATALYST FOR SYNTHESIS OF 1-(DIMETHYLAMINO)-3-ALKYL-2-PROPINES | 2008 |
|
RU2399413C2 |
| 4-(DIMETHYLAMINO)-1-ALKYL-1-METHYL-2-ALKYN-1-OLS SYNTHESIS METHOD | 2008 |
|
RU2378249C2 |
| METHOD OF PRODUCING α,ω-BIS-[2-(N,N-DIMETHYLAMINO)THIEN-5-YL]ALKANES | 2010 |
|
RU2434012C2 |
| METHOD OF PRODUCING SYMMETRICAL GEM-DIAMINES | 2008 |
|
RU2382027C2 |
