FIELD: chemistry.
SUBSTANCE: invention relates to a method for synthesis of chloroalkanes and chlorocycloalkanes via hydrochlorination of unsaturated compounds under the effect of chromium-containing catalysts Cr(acac)3, Cr(HCO2)3 and Cr(CO)6, activated with pyridine in a mediuim of carbon tetrachloride and water at 150°C for 6 hours in molar ratio [Cr]:[pyridine]:[olefin]:[CCl4]:[H2O]=1:1:100:100:2000.
EFFECT: output of monochloroalkanes and cycloalkanes equals 70-90%.
1 cl, 6 ex
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Authors
Dates
2010-10-27—Published
2008-08-06—Filed