METHOD FOR SYNTHESIS OF CHLOROALKANES AND CHLOROCYCLOALKANES VIA HYDROCHLORINATION OF UNSATURATED COMPOUNDS Russian patent published in 2010 - IPC C07C19/01 C07C23/02 C07C17/08 B01J23/26 

Abstract RU 2402518 C2

FIELD: chemistry.

SUBSTANCE: invention relates to a method for synthesis of chloroalkanes and chlorocycloalkanes via hydrochlorination of unsaturated compounds under the effect of chromium-containing catalysts Cr(acac)3, Cr(HCO2)3 and Cr(CO)6, activated with pyridine in a mediuim of carbon tetrachloride and water at 150°C for 6 hours in molar ratio [Cr]:[pyridine]:[olefin]:[CCl4]:[H2O]=1:1:100:100:2000.

EFFECT: output of monochloroalkanes and cycloalkanes equals 70-90%.

1 cl, 6 ex

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Authors

Dzhemilev Usein Memetovich

Khusnutdinov Ravil Ismagilovich

Shchadneva Nina Alekseevna

Oshnjakova Tat'Jana Mikhajlovna

Dates

2010-10-27Published

2008-08-06Filed