METHOD OF PRODUCING POLYMETHYLMETHACRYLATE VIA RADICAL POLYMERISATION IN METHYLMETHACRYLATE MASS Russian patent published in 2011 - IPC C08F120/14 

Abstract RU 2412950 C2

FIELD: chemistry.

SUBSTANCE: present invention relates to production of polymethylmethacrylate. The invention describes a method of producing polymethylmethacrylate through radical polymerisaton in a mass of methylmethacrylate in the presence of an initiating system consisting of an initiator and an additive which is a ferrocene derivative while heating, characterised by that the ferrocene derivative used is 1-[pyridyl-2]-ferrocene or 1-[quinolin-2-yl]ferrocene or 1-[acridin-9-yl]-ferrocene or 1-[pyrazin-2-yl]-ferrocene or 1-[pyrimidin-4-yl]-ferrocene in molar ratio of initiator to additive equal to (0.05-1.00):(0.05-1.5).

EFFECT: obtaining polymethylmethacrylate with improved molecular weight characteristics, elimination of the gel effect, low consumption of components of the initiating system.

1 cl, 3 dwg, 2 tbl, 15 ex

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Authors

Islamova Regina Maratovna

Golovochesova Olesja Ivanovna

Monakov Jurij Borisovich

Chupakhin Oleg Nikolaevich

Utepova Irina Aleksandrovna

Musikhina Aleksandra Aleksandrovna

Rusinov Vladimir Leonidovich

Dates

2011-02-27Published

2009-05-08Filed