FIELD: chemistry.
SUBSTANCE: invention relates to production of refractory materials and can be used in production of spinel-containing refractory materials for lining thermal generating units. The disclosed magnesia spinel-based fused material, which contains MgO, Al2O3, SiO2, CaO and Fe2O3, is characterised by that it also contains Cr2O3 with the following ratio of components in wt %: MgO - 25.0-30.0; SiO2 - 1.0-3.0; CaO- 1.0-4.0; Fe2O3 - 0.2-0.4; Cr2O3 - 10.0-20.0; Al2O3 - the rest. The method of producing magnesia spinel-based fused material involves mechanical processing a chromium-containing by-product of industrial production in form of slag from aluminium-thermal production of ferrochromium, with the following ratio of components in wt %: MgO 12.0-20.0; SiO210.0-16.0; CaO 18.0-30.0; Fe2O3 0.1-1.0; Cr2O3 5.0-10.0; Al2O3 - the rest, where the ratio CaO/SiO2 is less than 1.8. Mechanical processing is carried out by grating with separation of fractions larger than 100 mcm. Since crystals of the spinel in the said slag are concentrated in the large fraction, grating enables to obtain material which contains up to 97 wt % spinel.
EFFECT: obtaining magnesia spinel-based material with improved working characteristics using a simple method.
2 cl, 3 ex, 1 tbl
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Authors
Dates
2011-04-27—Published
2009-01-26—Filed