FIELD: chemistry.
SUBSTANCE: present invention relates to a method for synthesis of high-molecular alcohol with an even number of carbon atoms equal to 4 or more, involving bringing ethanol into contact with calcium phosphate for 0.6 seconds or more at 150°-450°C. The invention also relates to a method for synthesis of 1-butanol with selectivity equal to 70.3% or more, involving bringing ethanol into contact with calcium phosphate for 0.6 seconds or more at 200°C or higher but lower than 350°C, wherein calcium sulphate does not have a metallic carrier. As a rule, calcium phosphate is hydroxyapatite.
EFFECT: invention enables to obtain high-molecular alcohols using a highly efficient and ecologically clean method.
4 cl, 4 dwg, 1 tbl, 4 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR SYNTHESIS OF CHEMICAL INDUSTRY RAW MATERIAL AND FUEL COMPOSITIONS | 2008 |
|
RU2485087C2 |
CATALYST AND METHOD OF PROCESSING ETHANOL INTO LINEAR ALPHA-ALCOHOLS | 2015 |
|
RU2601426C1 |
METHOD OF OBTAINING COMPOSITION USING ALCOHOL AS RAW MATERIAL | 2008 |
|
RU2467057C2 |
AMINATION METHOD | 1998 |
|
RU2215734C2 |
LOW-VISCOSITY CONCENTRATED SOLUTIONS OF ALKALINE EARTH METAL ALKOXIDES IN APROTIC SOLVENTS AND PROCESSES FOR PREPARATION THEREOF | 2013 |
|
RU2658012C2 |
METHOD OF PREPARING OLEFINS | 1995 |
|
RU2131405C1 |
METHOD OF SYNTHESIS OF CHEMICAL INDUSTRIAL RAW MATERIAL AND HIGH-OCTANE FUEL, AND COMPOSITION OF HIGH-OCTANE FUEL | 1999 |
|
RU2191769C2 |
CATALYST AND METHOD OF ALKYLATING ETHANOL WITH ISOPROPANOL | 2015 |
|
RU2594162C1 |
METHOD FOR PRODUCING OLEFIN BY CATALYTIC CONVERSION OF AT LEAST ONE ALCOHOL | 2014 |
|
RU2660132C2 |
RECOMBINANT CELL PRODUCING 2-HYDROXYISOBUTYRIC ACID | 2009 |
|
RU2514672C9 |
Authors
Dates
2011-06-27—Published
2005-12-02—Filed