CATALYST AND METHOD OF ALKYLATING ETHANOL WITH ISOPROPANOL Russian patent published in 2016 - IPC B01J23/89 C07C31/125 C07C29/32 

Abstract RU 2594162 C1

FIELD: chemistry.

SUBSTANCE: invention relates to a catalyst and a method of alkylating ethanol with isopropanol to produce pentanol-2. Catalyst for alkylation of ethanol with isopropanol consists of γ-Al2O3, Cu or Ni and a second metal - Au in following proportions, wt%: Au - 0.2-0.5, Ni or Cu - 0.06-0.32, γ-Al2O3 - balance. Method of alkylating ethanol with isopropanol is carried out in an autoclave-type reactor in presence of said catalyst at partial pressure of ethanol and isopropanol of 61-100 atm, temperature of 240-295 °C for 1-8 hours while stirring constantly.

EFFECT: high selectivity of formation of end product - pentanol-2 - with high degree of conversion of initial alcohols, higher efficiency on target component, reduced time of contact.

3 cl, 4 tbl, 24 ex

Similar patents RU2594162C1

Title Year Author Number
CATALYST AND METHOD OF PROCESSING ETHANOL INTO LINEAR ALPHA-ALCOHOLS 2015
  • Chistjakov Andrej Valerevich
  • Zharova Polina Aleksandrovna
  • Nikolaev Sergej Aleksandrovich
  • Tsodikov Mark Veniaminovich
RU2601426C1
DEHYDROGENATION OF ALKANOLS FOR INCREASING OUTPUT OF AROMATIC SUBSTANCES 2011
  • Blommel Paul G.
  • Yuan Li
  • Van Straten Matt
  • Lyman Warren
  • Cortright Randy D.
RU2577855C2
METHOD OF PRODUCING TERT-BUTYL ALCOHOL 2019
  • Ivanov Dmitrii Petrovich
  • Dubkov Konstantin Aleksandrovich
  • Starokon Evgenii Vladimirovich
  • Piriutko Larisa Vladimirovna
  • Kharitonov Aleksandr Sergeevich
  • Noskov Aleksandr Stepanovich
RU2715430C1
METHOD OF PREPARING MIXTURE OF CYCLOHEXANOL AND CYCLOHEXANONE 2009
  • Kharitonov Aleksandr Sergeevich
  • Ivanov Aleksej Alekseevich
  • Chernjavskij Valerij Sergeevich
  • Pirjutko Larisa Vladimirovna
RU2402520C1
METHOD OF N-ALKYLATION OF CYCLIC AMINES 2016
  • Popov Yurij Vasilevich
  • Mokhov Vladimir Mikhajlovich
  • Latyshova Snezhana Evgenevna
  • Panov Aleksandr Olegovich
  • Shirkhanyan Petros Misakovich
RU2622296C1
P-XYLENE PRODUCTION PROCESS (VERSIONS) 1996
  • Mysov V.M.
  • Ione K.G.
RU2114811C1
METHOD OF TREATING POLYALKYL AROMATIC HYDROCARBONS 2020
  • Buzzoni, Roberto
  • Fois, Giovanni Antonio
RU2818090C2
METHOD FOR SELECTIVE PRODUCTION OF N-METHYL-PARA-ANISIDINE 2011
  • Frolov Aleksandr Jur'Evich
  • Ivanov Jurij Aleksandrovich
  • Beljakov Nikolaj Grigor'Evich
RU2472774C1
METHOD FOR SYNTHESIS OF HYDROCARBON COMPONENTS OF GASOLINE 2007
  • Jensen Finn
  • Nil'Sen Poul Ehrik Khejlund
  • Shied Nil'S Kristian
  • Janssens Ton V.V.
  • Voss Bodil'
RU2448147C2
METHOD FOR SELECTIVE PRODUCTION OF N-METHYL-PARA-ANISIDINE 2012
  • Frolov Aleksandr Jur'Evich
  • Ivanov Jurij Aleksandrovich
  • Beljakov Nikolaj Grigor'Evich
RU2508288C1

RU 2 594 162 C1

Authors

Chistyakov Andrej Valerevich

Zharova Polina Aleksandrovna

Nikolaev Sergej Aleksandrovich

Tsodikov Mark Veniaminovich

Dates

2016-08-10Published

2015-05-18Filed