FIELD: chemistry.
SUBSTANCE: invention relates to a catalyst and a method of alkylating ethanol with isopropanol to produce pentanol-2. Catalyst for alkylation of ethanol with isopropanol consists of γ-Al2O3, Cu or Ni and a second metal - Au in following proportions, wt%: Au - 0.2-0.5, Ni or Cu - 0.06-0.32, γ-Al2O3 - balance. Method of alkylating ethanol with isopropanol is carried out in an autoclave-type reactor in presence of said catalyst at partial pressure of ethanol and isopropanol of 61-100 atm, temperature of 240-295 °C for 1-8 hours while stirring constantly.
EFFECT: high selectivity of formation of end product - pentanol-2 - with high degree of conversion of initial alcohols, higher efficiency on target component, reduced time of contact.
3 cl, 4 tbl, 24 ex
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Authors
Dates
2016-08-10—Published
2015-05-18—Filed