CATALYST AND METHOD OF PROCESSING ETHANOL INTO LINEAR ALPHA-ALCOHOLS Russian patent published in 2016 - IPC B01J23/89 B01J21/04 C07C29/34 C07C31/12 C07C31/125 

Abstract RU 2601426 C1

FIELD: chemistry.

SUBSTANCE: present invention relates to a catalyst for synthesis of linear alpha-alcohols containing an even number of carbon atoms, from ethanol, consisting of γ-Al2O3, Cu or Ni and a second metal, characterised by that as second metal it contains Au with following content of components, wt%: Au - 0.05-0.15; Ni or Cu - 0.015-0.1; γ-Al2O3 - balance. Invention also relates to a method for direct synthesis of linear alpha-alcohols containing an even number of carbon atoms, in presence of disclosed catalyst in autoclave reactor at partial pressure of ethanol of 61-100 atm, temperature of 240-295 °C for 1-8 hours with constant stirring and cooling to room temperature while stirring constantly.

EFFECT: disclosed objects increase selectivity and specific capacity on output of linear alpha-alcohols while maintaining high degree of conversion of ethanol.

2 cl, 4 tbl, 23 ex

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RU 2 601 426 C1

Authors

Chistjakov Andrej Valerevich

Zharova Polina Aleksandrovna

Nikolaev Sergej Aleksandrovich

Tsodikov Mark Veniaminovich

Dates

2016-11-10Published

2015-05-18Filed