FIELD: chemistry.
SUBSTANCE: method for industrial production of pure MgCO3 involves crushing olivine-containing rock and bringing the crushed rock into contact with water and CO2. At the first step, which is carried out under pressure, a dissolution reaction takes place according to the equation Mg2SiO4(s)+4H+=2Mg2++SiO2(aq)+2H2O. At the second step, deposition is carried out at higher pH. The following reactions take place: Mg2++HCO3 -=MgCO3(s)+H+ and Mg2++CO3 2-=MgCO3(s). The presence of HCO3 - and H+ ions is mainly a result of reaction of CO2 and water.
EFFECT: invention enables to produce pure magnesium carbonate from rock while binding free carbon dioxide gas.
19 cl, 4 dwg, 2 tbl, 2 ex
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Authors
Dates
2011-12-27—Published
2006-11-23—Filed