METHODS OF PRODUCING ORGANIC COMPOUND OF ALKALI METAL AND ORGANIC COMPOUND OF TRANSITION METAL Russian patent published in 2012 - IPC C07F1/02 C07F17/00 

Abstract RU 2445316 C1

FIELD: chemistry.

SUBSTANCE: method involves adding an olefin compound of formula (2) into a reaction containing an active proton of a compound of formula (1), with an alkali metal compound RHP (I), where R denotes a hydrocarbon group or an amino group and can contain a halogen atom, a silicon atom, an oxygen atom or a nitrogen atom, H denotes an active proton and p denotes the number of hydrogen atoms participating in the reaction with the alkali metal compound, where each of Ra-Rc denotes an atom or a group selected from a hydrogen atom, a hydrocarbon group, a group containing a heteroatom, and a silicon-containing group, and can be identical or different and adjacent substitutes can be bonded with each other to form a ring, RNp (3), where R denotes a hydrocarbon group or an amino group and can contain a halide atom, a silicon atom, an oxygen atom or a nitrogen atom, N denotes an alkali metal atom and p can also assume the same value as in formula (1), where Ra in formula (2) denotes an aryl group, where the alkali metal compound is represented by formula (4): AN (4), where A denotes a hydrocarbon group containing 1-15 carbon atoms and N is an alkali metal atom. Disclosed also is a method of producing an organic compound of a transition metal.

EFFECT: obtaining an organic compound of an alkali metal with high output.

6 cl, 14 ex

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RU 2 445 316 C1

Authors

Sakuma Atsusi

Funaja Munekhito

Dates

2012-03-20Published

2008-12-02Filed