FIELD: chemistry.
SUBSTANCE: method involves transfer of manganese and accompanying impurities into a solution through two-step treatment of the starting material with hydrochloric acid and absorption of chlorine with an alkaline solution. Further, impurities are separated to obtain a manganese salt solution which is then treated. The first step uses waste hydrochloric acid with concentration 1-10% with solid to liquid ratio equal to 1:(3-5). A manganese-containing residue is separated from the obtained pulp, where said residue is then treated at the second step with waste inhibited hydrochloric acid with concentration 20-24% and content of inhibitor of not less than 5 wt %, reaction with iron of which results in insoluble complex compounds, where said inhibitor is in form of quaternary ammonium salts, with molar ratio manganese:HCl=1.0:1.1. The insoluble residue of aluminosilicates is then separated and the manganese salt solution is then processed using existing methods.
EFFECT: obtaining high-quality products.
5 cl, 2 tbl, 2 ex
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Authors
Dates
2012-04-20—Published
2010-12-22—Filed