FIELD: chemistry.
SUBSTANCE: method involves reaction of a terminal olefin with an oxidising agent in the presence of a catalyst in a two-phase system which contains an organic phase and aqueous reaction medium, the catalyst containing a water-soluble manganese complex, the terminal olefin having solubility at 20°C of at least 0.01-100 g per litre of water, and molar ratio of the terminal olefin to the oxidising agent ranging from 1:0.1 to about 1:1.
EFFECT: method enables to obtain an end product with large number of revolutions and high selectivity.
20 cl, 6 ex, 5 tbl
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PRODUCING EPICHLOROHYDRIN USING HYDROGEN PEROXIDE AND MANGANESE COMPLEX | 2009 |
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| METHOD FOR CATALYTIC EPOXIDATION | 2013 |
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| OBTAINING EPOXYETHYLCARBOXYLATE OR GLYCIDYLCARBOXYLATE | 2011 |
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RU2542583C2 |
| METHOD OF EPOXIDATION OF OLEFIN-UNSATURATED COMPOUNDS | 2012 |
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| METHOD OF PRODUCING PROPYLENE OXIDE | 2010 |
|
RU2528385C2 |
| OBTAINING EPOXYETHYL ETHERS OR GLYCIDYL ETHERS | 2011 |
|
RU2532267C2 |
| OLEFIN EPOXIDATION PROCESS | 1996 |
|
RU2162466C2 |
| WATER HYDROGEN PEROXIDE SOLUTION, METHOD OF ITS OBTAINING AND ITS APPLICATION | 2008 |
|
RU2468990C2 |
