FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing epoxy compounds, which includes adding an oxidant, a water-soluble manganese complex and terminal olefin to obtain a polyphase reaction mixture; reacting the terminal olefin and oxidant in the polyphase reaction mixture comprising at least one organic phase, in the presence of the water-soluble manganese complex; dividing the reaction mixture into at least one organic phase and an aqueous phase and recycling at least a portion of the aqueous phase. The water-soluble manganese complex is a mononuclear particle of general formula (I): [LMnX3]Y, or a binuclear particle of general formula (II): [[LMn(µ-X3)MnL](Y)n, where Mn is manganese; L or each L is independently a polydentate ligand; each X is independently a coordinating particle and each µ-X is independently a bridging coordinating particle, and where Y is a non-coordinating counterion.
EFFECT: efficient use of the catalyst and high end product selectivity of the process.
17 cl, 1 dwg, 1 tbl, 5 ex
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Authors
Dates
2015-02-10—Published
2011-01-26—Filed