FIELD: chemistry.
SUBSTANCE: method includes reaction in the first multiphase system of an olefin-unsaturated compound with an oxidant in the presence of a buffer component and a water-soluble manganese complex, which is in a water phase having the first level of pH, constituting from more than 2.5 to 6 in the first multiphase system; regulation of the water phase pH to the second pH level lower than the first pH level which constitutes 2.5 or less; separation of, at least, a part of the water phase from the first multiphase system; regulation of pH of the said, at least, a part of the water phase to the third pH level higher than the second pH level and constituting from more than 2.5 to 6; and introduction of the said, at least, a part of the water phase into the second multiphase system.
EFFECT: preservation of the catalyst activity in the process of epoxidation.
11 cl, 3 dwg, 7 tbl
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Authors
Dates
2015-09-10—Published
2012-06-13—Filed