FIELD: chemistry.
SUBSTANCE: invention relates to field of catalysis. Described is catalyst of dismutation of water and halogen-containing silicon compounds, which contains as carrier silicon dioxide and/or zeolite and at least one linear, cyclic, branched and/or cross-linked aminoalkyl-functional siloxane and/or silanol, which in idealised formula corresponds to general formula (II): (R2)[-O-(R4)Si(A)]aR3·(HW)W (II), where A stands for aminoalkyl residue -(CH2)3-N(R1)2 with similar or different R1, representing isobutyl, tert-butyl and/or cyclohexyl, R2 independent on each other represent hydrogen, methyl, ethyl, n-propyl, isopropyl and/or Y, R3 and R4 independent on each other represents hydroxy, methoxy, ethoxu, n-propoxy, isopropoxy, methyl, ethyl, n-propyl, isopropyl and/or -OY, with Y representing carrier material, HW represent acid, with W standing for halogenide, residue of silicic acid, sulphate and/or carboxylate, with a≥1 in case of silanol, a≥2 in case of siloxane and w≥0. Method of obtaining said catalyst, its application in process of dismutation and installation for dismutation with its application are described.
EFFECT: reduction of economical expenditures of dismutation process.
17 cl, 1 dwg, 2 tbl, 7 ex
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Authors
Dates
2013-09-20—Published
2008-10-08—Filed