GAS-PHASE POLYMERISATION METHOD HAVING MULTIPLE FLOW MODES Russian patent published in 2014 - IPC C08F10/06 

Abstract RU 2519752 C2

FIELD: chemistry.

SUBSTANCE: invention relates to an improved method for gas-phase polymerisation of olefins in two or more flow modes. Described is a method of producing polypropylene or propylene copolymer, which involves polymerisation of propylene in a reactor. The reactor has two or more different flow modes. One of the flow modes has volume content of the solid phase in a multi-phase stream greater than 15%. A system based on a mixed external electron donor is fed into the reactor, where the system contains at least one selectivity control agent and at least one activity limiting agent. A catalyst system further includes an aluminium-containing co-catalyst, where molar ratio of aluminium to the mixed external electron donor is in the range of 0.5-4.0:1.

EFFECT: preventing agglomeration of particles in the reactor and formation of polymer agglomerates.

17 cl, 1 tbl, 4 ex

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RU 2 519 752 C2

Authors

Tsaj Pin

Chehn' Lin'Fehn

Van Ehgmond Jan V.

Tilston Majkl V.

Dates

2014-06-20Published

2010-12-16Filed