FIELD: chemistry.
SUBSTANCE: invention relates to electroplating and can be used in producing semiconductors. The composition contains at least one copper ion source and at least one additive obtained by reacting a) a compound of a polyatomic alcohol condensate obtained from at least one polyalcohol of formula X(OH)m (I) via condensation with b) at least one alkylene oxide to produce a polyatomic alcohol condensate containing polyoxyalkylene side chains, where m is an integer from 3 to 6, and X is an m-valent linear or branched aliphatic or cycloaliphatic radical having 2 to 10 carbon atoms, which can be substituted or unsubstituted. The method includes contacting an electrolytic bath containing said composition with a substrate, generating current density in the substrate during a period of time sufficient for depositing a metal coating.
EFFECT: filling nanometre channels and openings substantially without defects.
15 cl, 6 dwg, 6 ex
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Authors
Dates
2015-01-27—Published
2010-07-16—Filed