FIELD: chemistry.
SUBSTANCE: invention relates to the field of organic chemistry, namely to a method of obtaining bis-(3-methoxybenzamidyl)-tetrathiazacycloalkanes of formula 
(1), where n=1 or 2, characterised by the fact that meta-methoxybenzhydraside is subjected to interaction with α,ω-dithiol [HS(CH2)3(CH2)nSH, where n=1, 2], preliminarily mixed at 20°C with a water solution of formaldehyde, in the presence of a catalyst of samarium chloride crystallohydrate SmCl3·6H2O with the molar ratio of hydrazide : α,ω-alkanedithiol : formaldehyde : SmCl3·6H2O=10:10:20:(0.3-0.7), preferably 10:10:20:0.5 at 75-85°C and atmospheric pressure for 20-26 h.
EFFECT: elaborated is the method of obtaining bis-(3-methoxybenzamidyl)-tetrathiazacycloalkanes, which can be applied as biologically active compounds, selective sorbents and extractants of noble and precious metals.
1 tbl
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF OBTAINING N,N'-BIS-(3-MERCAPTOPHENYL)TETRATHIADIAZACYCLOALKANES | 2013 |
|
RU2538595C1 |
| METHOD OF OBTAINING N, N'-BIS-(2-HYDROXYETHYL)TETRATHIADIAZACYCLOALKANES, DEMONSTRATING FUNGICIDAL ACTIVITY | 2013 |
|
RU2541793C2 |
| METHOD OF PRODUCING S,S'-BIS([N,N-DIMETHYL]METHYL)ALKANEDITHIOLS | 2010 |
|
RU2464259C2 |
| METHOD OF OBTAINING A, α,ω-BIS-(1, 5, 3-DITHIAZEPINAN-3-YL)ALKANES | 2011 |
|
RU2466999C1 |
| METHOD OF PRODUCING α,ω -BIS-(1,5,3-DITHIAZEPINAN-3-YL)ALKANES | 2011 |
|
RU2478634C2 |
| METHOD FOR PRODUCING 2-{[({2-[({[2-(AMINOCARBONYL)PHENYL]AMINO}METHYL)THIO]ALKYL}THIO)-METHYL]AMINO}BENZAMIDES | 2021 |
|
RU2779385C2 |
| METHOD OF PRODUCING N,N-BIS-[(1,5,3-DITHIAZEPAN-3-YL)ALKYL]AMINES | 2014 |
|
RU2591196C2 |
| METHOD OF OBTAINING 1,7-DITHIA-3,5-DIASACYCLOALKAN-4-(THI)ONES | 2013 |
|
RU2551687C1 |
| METHOD OF OBTAINING 1,7-DITHIA-3,5-DIASACYCLOALKAN-4-ONES | 2013 |
|
RU2551685C1 |
| METHOD OF PRODUCING 1,7-DITHIA-3,5-DIAZACYCLOALKAN-4-ONES | 2014 |
|
RU2565778C1 |
