FIELD: chemistry.
SUBSTANCE: invention relates to materials for the jewellery industry. A transparent, semitransparent or nontransparent composite nanocrystalline material based on nanosized oxide and silicate crystalline phases contains one of the following crystalline phases: spinel, quartz-like phases, sapphirine, enstatite, petalite-like phase, cordierite, willemite, zirconium, rutile, zirconium titanate, zirconium dioxide with content of ions of transition elements, rare-earth elements and precious metals of 0.001 to 4 mol%. One of the crystalline phases is additionally quartz-like solid solutions of lithium magnesium zinc aluminosilicates with a virgilite structure of the following composition, mol%: SiO2 - 45-72; Al2O3 - 15-30; MgO - 0.1-23.9; ZnO - 0.1-29; Li2O - 1-18; PbO - 0.1-7.0; ZrO2 - 0.1-10; TiO2 - 0.1-15; NiO - 0.001-4.0; CoO - 0.001-3.0; CuO - 0.001-4.0; Cr2O3 - 0.001-1.0; Bi2O3 - 0.001-3.0; Fe2O3 - 0.001-3.0; MnO2 - 0.001-3.0; CeO2 - 0.001-3.0; Nd2O3 - 0.001-3.0; Er2O3 - 0.001-3.0; Pr2O3 - 0.001-3.0; Au - 0.001-1.0.
EFFECT: invention increases heat resistance and reduces the coefficient of thermal expansion.
2 tbl
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Authors
Dates
2015-03-27—Published
2013-05-13—Filed