FIELD: chemistry.
SUBSTANCE: invention refers to agents for nitrate-comprising liquid radioactive waste (LRW) processing and can be used at nuclear power plants and specialised plants conditioning low and mean-active radioactive waste. In the declared method, before hardening in inorganic or polymer matrix material, the nitrate-containing LRW is biodegradable by the enzymatic processes with specially selected consortia of microorganisms with added phosphoric acid and saccharose; the microorganisms recover nitrate ions to molecular nitrogen, whereas a non-radioactive gas phase (nitrogen, carbon dioxide) is dumped. The radioactive nuclides are absorbed by biomass slag formed by the biodegradation and consisting of the microorganisms and their metabolites; phosphoric acid promotes carrying out the denitrification processes and additionally leads to strontium phosphate sedimentation that provides higher strength of the cement matrix.
EFFECT: reducing the amount of nitrate-containing LRW before added to the inorganic (cement, ceramic) or polymer matrix, reducing the amount of long-storage (burial) final product, preventing biodegradation of nitrate-containing LRW as a part of long-storage cement compound.
3 cl, 1 tbl, 2 dwg
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Authors
Dates
2015-06-10—Published
2013-05-30—Filed